Capture, Convert Carbon Dioxide for Fuel

Monday, August 10, 2015 @ 05:08 PM gHale

When it comes to carbon dioxide, the words capture and convert sum it all up.

That is because that is the process that stops the greenhouse gas before it escapes from chimneys and power plants into the atmosphere and turns it into a useful product.

One possible end product is methanol, a liquid fuel and the focus of a study conducted at the U.S. Department of Energy’s (DoE) Argonne National Laboratory.

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The chemical reactions that make methanol from carbon dioxide rely on a catalyst to speed up the conversion, and Argonne scientists identified a new material that could fill this role. With its structure, this catalyst can capture and convert carbon dioxide in a way that ultimately saves energy.

Enter the copper tetramer. It consists of small clusters of four copper atoms each, supported on a thin film of aluminum oxide. These catalysts work by binding to carbon dioxide molecules, orienting them in a way that is ideal for chemical reactions. The structure of the copper tetramer is such that most of its binding sites are open, which means it can attach more strongly to carbon dioxide and can better accelerate the conversion.

The current industrial process to reduce carbon dioxide to methanol uses a catalyst of copper, zinc oxide and aluminum oxide. A number of its binding sites end up occupied merely in holding the compound together, which limits how many atoms can catch and hold carbon dioxide.

“With our catalyst, there is no inside,” said Stefan Vajda, senior chemist at Argonne and the Institute for Molecular Engineering and co-author of a paper on the subject. “All four copper atoms are participating because with only a few of them in the cluster, they are all exposed and able to bind.”

To compensate for a catalyst with fewer binding sites, the current method of reduction creates high-pressure conditions to facilitate stronger bonds with carbon dioxide molecules. But compressing gas into a high-pressure mixture takes a lot of energy.

Multiple benefits
The benefits of enhanced binding is the new catalyst requires lower pressure and less energy to produce the same amount of methanol.

Carbon dioxide emissions are an ongoing environmental problem, and according to the authors, it’s important that research identifies optimal ways to deal with the waste.

“We’re interested in finding new catalytic reactions that will be more efficient than the current catalysts, especially in terms of saving energy,” said Larry Curtiss, an Argonne Distinguished Fellow who co-authored this paper.

Copper tetramers could allow us to capture and convert carbon dioxide on a larger scale — reducing an environmental threat and creating a useful product like methanol that can transport and burn for fuel.

This is just the beginning, though as the catalyst still has a long journey from the lab to industry.

Potential obstacles include instability and figuring out how to manufacture mass quantities. There’s a chance that copper tetramers may decompose when put to use in an industrial setting, so ensuring long-term durability is a critical step for future research, Curtiss said. And while the scientists needed only nanograms of the material for this study, that number would have to be multiplied dramatically for industrial purposes.

Meanwhile, the researchers are interested in searching for other catalysts that might even outperform their copper tetramer.

These catalysts can vary in size, composition and support material, which results in a list of more than 2,000 potential combinations, Vajda said.

But the scientists don’t have to run thousands of different experiments, said Peter Zapol, an Argonne physicist and co-author of this paper. Instead, they will use advanced calculations to make predictions, and then test the catalysts that seem most promising.

“We haven’t yet found a catalyst better than the copper tetramer, but we hope to,” Vajda said. “With global warming becoming a bigger burden, it’s pressing that we keep trying to turn carbon dioxide emissions back into something useful.”