Combing Out Contaminants

Thursday, August 12, 2010 @ 09:08 AM gHale


A mere trace of contaminants can damage or ruin tiny devices in the semiconductor industry. So, that means manufacturers need to detect minute traces of contaminant molecules in the arsine gas used to make a variety of photonics devices.
And that is where cavity-enhanced direct frequency comb spectroscopy (CE-DFCS) comes in, said researchers at JILA, a joint institute of the National Institute of Standards and Technology (NIST) and the University of Colorado at Boulder (CU). It acts as a fine-toothed comb to detect these contaminant molecules. It consists of an optical frequency comb — a tool for accurately generating different colors, or frequencies, of light — adapted to analyze the quantity, structure and dynamics of various atoms and molecules simultaneously. The technique offers a combination of speed, sensitivity, specificity and broad frequency coverage.
The semiconductor industry needs to find traces of water and other impurities in arsine gas used in manufacturing of III-V semiconductors for light-emitting diodes (LEDs), solar-energy cells and laser diodes for DVD players.
The contaminants can alter a semiconductor’s electrical and optical properties. For instance, water vapor can add oxygen to the material, reducing device brightness and reliability. Traces of water are hard to identify in arsine, which absorbs light in a complex, congested pattern across a broad frequency range. Most analytical techniques have significant drawbacks, such as large and complex equipment or a narrow frequency range.
The JILA comb system, previously demonstrated as a “breathalyzer” for detecting disease, got an upgrade to access longer wavelengths of light, where water strongly absorbs and arsine does not, to better identify the water.
In the JILA experiments, arsine gas went in an optical cavity where light pulses “combed” through it. The atoms and molecules inside the cavity absorbed some light energy at frequencies where they switch energy levels, vibrate or rotate. The comb’s “teeth” precisely measured the intensity of different shades of infrared light before and after the interactions. By detecting which colors the teeth absorbed and in what amounts — matched against a catalog of known absorption signatures for different atoms and molecules — the researchers could measure water concentration to very low levels.
Just 10 water molecules per billion molecules of arsine can cause semiconductor defects. The researchers detected water at levels of 7 molecules per billion in nitrogen gas, and at 31 molecules per billion in arsine. The researchers are now working on extending the comb system even further into the infrared and aiming for parts-per-trillion sensitivity.
The Air Force Office of Scientific Research, Defense Advanced Research Projects Agency, Defense Threat Reduction Agency, Agilent Technologies, and NIST funded the research.



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