Tandem Solar Cells Work Better

Tuesday, December 1, 2015 @ 04:12 PM gHale

Stacking two solar cells one on top of the other, where top cell is semi-transparent, which efficiently converts large energy photons into electricity, while the bottom cell converts the remaining or transmitted low energy photons in an optimum manner.

This allows a larger portion of the light energy to convert to electricity.

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Up to now, the sophisticated technology needed for the procedure mainly focused on the realm of space or concentrated photovoltaics (CPV). These “tandem cells” grown on very expensive single crystal wafers are not attractive for mass production and low cost solar electricity.

The research team working under Stephan Buecheler and Ayodhya N. Tiwari from the Laboratory for Thin Films and Photovoltaics at Empa-Swiss Federal Laboratories for Material Science and Technology has now succeeded in making tandem solar cells based on polycrystalline thin films, and the methods are suitable for large area low cost processing.

Flexible plastic or metal foils could also end up used as substrate in future. This marks a major milestone on the path to mass production of high-efficiency solar cells with low cost processes.

The secret behind the new process is researchers create the top solar cell perovskite film with a low-temperature procedure at just 50 degrees Celsius. This promises an energy-saving and cost-saving production stage for future manufacturing processes. The tandem solar cell yielded an efficiency rate of 20.5 percent when converting light to electricity. Already with this first attempt Empa researchers said it has lots more potential to offer for better conversion of solar spectrum into electricity.

The key to this double success was the development of a 14.2 percent efficient semi-transparent solar cell, with 72 percent average transparency, made from methylammonium lead iodide deposited in the form of tiny perovskite crystals.

The perovskite ends up grown on a thin interlayer made of the substance abbreviated as PCBM (phenyl-C61-butyric acid methyl ester).

Each PCBM molecule contains 61 carbon atoms interconnected in the shape of a soccer ball. The perovskite film ends up prepared by a combination of vapor deposition and spin coating onto this layer, which has tiny football like structure, followed by an annealing at a “lukewarm” temperature.

This perovskite crystal absorbs blue and yellow spectrum of visible light and converts these into electricity. By contrast, red light and infrared radiation simply pass through the crystal. As a result, the researchers can attach a further solar cell underneath the semi-transparent perovskite cell in order to convert the remaining light into electricity.

For the lower layer of the tandem solar cell, the Empa researchers use a CIGS cell (copper indium gallium diselenide), a technique that the team has been researching for years.

Based on the CIGS cells, small-scale production is already under way for flexible solar cells. The advantage of tandem solar cells is they exploit sunlight better. A solar cell can only convert radiation with an energy level higher than the bandgap of the semiconductor used. If the radiation energy is lower, no electricity ends up generated. If the radiation is higher in energy, the excess radiated energy converts to heat and is lost. A double-layer solar cell like Empa’s perovskite CIGS cell can combine substances with differing bandgaps and thus efficiently convert a larger share of the incident solar energy to electricity.

While very good single-layer polycrystalline solar cell may practically convert a maximum of 25 percent of the solar energy to electricity, tandem solar cells could increase this figure to beyond 30 percent. That’s according to Ayodhya Tiwari, head of the Thin Film and Photovoltaics laboratory.

“What we have achieved now is just the beginning,” Tiwari said. “We will have to overcome many obstacles before reaching this ambitious goal. To do this, we will need lots of interdisciplinary experience and a large number of combinatorial experiments until we have found a semi-transparent high-performance cell together with the right base cell, and technologies for electrical interconnections of these solar cells.”

Stephan Bücheler, who coordinates the lab research in Tiwari’s team, said the race for efficiency in solar cell research is certainly not just an academic endeavor.

“When producing solar-powered electricity, only half of the costs are down to the solar module itself,” Bücheler said. “The other half are incurred for the infrastructure: Inverters, cables, carriers for the cells, engineering costs and installation. These ancillary costs are reduced when the solar cells become more efficient and can be built in smaller sizes as a result. This means that efficient solar cells are the key to low-cost renewable electricity.”