Conventional silicon-based security primitives, such as True Random Number Generators (TRNGs) and Physical Unclonable Functions (PUFs), rely on microscopic physical quirks to create uncopyable device IDs and random encryption keys. However, their internal circuits suffer from severe performance degradation and rising bit error rates above 85°C, leaving critical infrastructure vulnerable to spoofing and data theft.
To handle that, researchers created a compact security component made of stacked metal oxides that produces reliable hardware fingerprints and cryptographic keys across a broad temperature span from -50C to 150C.
Prof. Yishu Zhang in Zhejiang University and his team addressed this bottleneck by stacking a 10-nanometer film of hafnium oxide atop a 40-nanometer film of tungsten oxide, sandwiched neatly between platinum and titanium nitride contacts.
Microscopic Turnstile
This multi-layer sandwich functions like an automatic microscopic turnstile. The natural energy mismatch across its interfaces lets forward signals pass freely while strangling backward electrical leaks down to a mere trillionth of an ampere, establishing a built-in one-way gate without requiring a separate control transistor.
Inside the oxide core, missing oxygen atoms act as stepping stones that line up under a voltage pulse to form a temporary conductive pathway. When the voltage turns off, these pathways naturally dissolve.
Because manufacturing leaves every single device with a slightly different microscopic texture, each bridge collapses at its own distinct pace. This unique decay time acts as a permanent hardware fingerprint, while the microscopic electrical fluctuations running through the signal provide a steady stream of random data for generating encryption keys.
Across an extreme 200°C testing range, spanning temperatures colder than an Antarctic blizzard to well beyond the boiling point of water, the system maintained stable security metrics.

Conceptual overview of the self-rectifying memristor crossbar array that monolithically integrates both true random number generator and physical unclonable function on a single 32-by-32 passive array, maintaining uncompromised security performance from minus 50 degrees Celsius to 150 degrees Celsius for next-generation Internet of Things deployed in military, aerospace, automotive, and industrial harsh environments.
Source: Paper authors
Its hardware fingerprint kept an error rate of 0.01859 percent at peak heat and ran with zero errors at room temperature across 100,000 test cycles without needing software corrections and achieved zero bit errors at room temperature across 100,000 test cycles without needing software error correction – a record for memristor-based PUFs.
Can’t Predict Output
At the same time, attacking machine-learning algorithms could not predict the output of the random number generator, achieving only a 50 percent accuracy rate equivalent to guessing on a coin toss.
Because the design works without external selector transistors, chip foundries can manufacture these arrays using standard sputtering equipment already present in existing production lines.
For the public, this translates into sturdier security hardware for automotive networks, power grids, and remote monitoring stations exposed to harsh field environments.
The next step toward commercial adoption involves scaling these prototype 32-by-32 grids into larger multi-kilobit arrays and integrating the necessary signal-amplification circuits directly onto complete and packaged silicon chips.
Click here to view the paper on the subject.

